You can use @ConfigurationProperties to have values from application.properties bound into a bean. To do so you annotate your @Bean method that creates the bean:
@Bean
@ConfigurationProperties
public BasicAuthAuthorizationInterceptor interceptor() {
    return new BasicAuthAuthorizationInterceptor();
}
As part of the bean's initialisation, any property on BasicAuthAuthorizationInterceptor will be set based on the application's environment. For example, if this is your bean's class:
public class BasicAuthAuthorizationInterceptor {
    private Map<String, String> users = new HashMap<String, String>();
    public Map<String, String> getUsers() {
        return this.users;
    }
}
And this is your application.properties:
users.alice=alpha
users.bob=bravo
Then the users map will be populated with two entries: alice:alpha and bob:bravo.
Here's a small sample app that puts this all together:
import java.util.HashMap;
import java.util.Map;
import org.springframework.boot.SpringApplication;
import org.springframework.boot.autoconfigure.EnableAutoConfiguration;
import org.springframework.boot.context.properties.ConfigurationProperties;
import org.springframework.boot.context.properties.EnableConfigurationProperties;
import org.springframework.context.annotation.Bean;
import org.springframework.context.annotation.Configuration;
@Configuration
@EnableAutoConfiguration
@EnableConfigurationProperties
public class Application {
    public static void main(String[] args) throws Exception {
        System.out.println(SpringApplication.run(Application.class, args)
                .getBean(BasicAuthAuthorizationInterceptor.class).getUsers());
    }
    @Bean
    @ConfigurationProperties
    public BasicAuthAuthorizationInterceptor interceptor() {
        return new BasicAuthAuthorizationInterceptor();
    }
    public static class BasicAuthAuthorizationInterceptor {
        private Map<String, String> users = new HashMap<String, String>();
        public Map<String, String> getUsers() {
            return this.users;
        }
    }
}
Take a look at the javadoc for ConfigurationProperties for more information on its various configuration options. For example, you can set a prefix to divide your configuration into a number of different namespaces:
@ConfigurationProperties(prefix="foo")
For the binding to work, you'd then have to use the same prefix on the properties declared in application.properties:
foo.users.alice=alpha
foo.users.bob=bravo