Here is a solution using selenium and special command for GhostDriver
(it should work since GhostDriver 1.1.0 and PhantomJS 1.9.6, tested with PhantomJS 1.9.8):
#!/usr/bin/env python
# -*- coding: utf-8 -*-
"""Download a webpage as a PDF."""
from selenium import webdriver
def download(driver, target_path):
    """Download the currently displayed page to target_path."""
    def execute(script, args):
        driver.execute('executePhantomScript',
                       {'script': script, 'args': args})
    # hack while the python interface lags
    driver.command_executor._commands['executePhantomScript'] = ('POST', '/session/$sessionId/phantom/execute')
    # set page format
    # inside the execution script, webpage is "this"
    page_format = 'this.paperSize = {format: "A4", orientation: "portrait" };'
    execute(page_format, [])
    # render current page
    render = '''this.render("{}")'''.format(target_path)
    execute(render, [])
if __name__ == '__main__':
    driver = webdriver.PhantomJS('phantomjs')
    driver.get('http://stackoverflow.com')
    download(driver, "save_me.pdf")
see also my answer to the same question here.