TryMe::arr is odr-used but you don't provide a definition (see it live):
constexpr int TryMe::arr[1];
Why is the result inconsistent between gcc and clang? This is because odr violations do not require a disagnostic, from both the C++11 and C++14 draft standard (emphasis mine):
Every program shall contain exactly one definition of every non-inline
  function or variable that is odr-used in that program; no diagnostic
  required.
We can see it is odr-used from the draft C++11 standard, section 3.2 which says:
An expression is potentially evaluated unless it is an unevaluated
  operand (Clause 5) or a subexpression thereof. A variable whose name
  appears as a potentially-evaluated expression is odr-used unless it is
  an object that satisfies the requirements for appearing in a constant
  expression (5.19) and the lvalue-to-rvalue conversion (4.1) is
  immediately applied.
TryMe::arr is an object and it does satisfy the requirements for appearing in a constant expression but the lvalue-to-rvalue conversion is not immediately applied to TryMe::arr but to TryMe::arr[0].
The updated wording from the draft C++14 standard which applies to C++11 as well since it was applied via a defect report(DR 712):
A variable x whose name appears as a potentially-evaluated expression
  ex is odr-used unless applying the lvalue-to-rvalue conversion (4.1)
  to x yields a constant expression (5.19) that does not invoke any
  non-trivial functions and, if x is an object, ex is an element of the
  set of potential results of an expression e, where either the
  lvalue-to-rvalue conversion (4.1) is applied to e, or e is a
  discarded-value expression
The potential results of the expression TryMe::arr[0] is empty by the criteria in 3.2 paragraph 2 and so it is odr-used.
Note: you need to provide a definition outside of the class as per section 9.4.2 [class.static.data] which says (emphasis mine):
A static data member of literal type can be declared in the class
  definition with the constexpr specifier; if so, its declaration shall
  specify a brace-or-equal-initializer in which every initializer-clause
  that is an assignment-expression is a constant expression. [ Note: In
  both these cases, the member may appear in constant expressions. —end
  note ] The member shall still be defined in a namespace scope if it
  is odr-used (3.2) in the program and the namespace scope definition
  shall not contain an initializer
Update
T.C. pointed out defect report 1926 which adds the following bullet to 3.2 [basic.def.odr] paragraph 2:
- If e is a subscripting operation (5.2.1 [expr.sub]) with an array operand, the set contains that operand.
 
Which means subscripting an array is no longer an odr-use and so the OPs code would be well-formed in C++1z and it seems like C++14 since the defect looks like it is against C++14.