It's an intrinsic, defined implicitly by the compiler itself (hence why it's called a builtin). It's documented on the language extension section for Clang:
__builtin_operator_new and __builtin_operator_delete
__builtin_operator_new allocates memory just like a non-placement non-class new-expression. This is exactly like directly calling the normal non-placement ::operator new, except that it allows certain optimizations that the C++ standard does not permit for a direct function call to ::operator new (in particular, removing new / delete pairs and merging allocations).
Likewise, __builtin_operator_delete deallocates memory just like a non-class delete-expression, and is exactly like directly calling the normal ::operator delete, except that it permits optimizations. Only the unsized form of __builtin_operator_delete is currently available.
These builtins are intended for use in the implementation of std::allocator and other similar allocation libraries, and are only available in C++.