If you want to do it without win32api, you can use the built-in ctypes module. I usually run CPython without win32api, so I kinda like these solutions.
It's a tiny bit more work for GetSystemPowerStatus() because you have to define the SYSTEM_POWER_STATUS structure, but not bad.
# Get power status of the system using ctypes to call GetSystemPowerStatus
import ctypes
from ctypes import wintypes
class SYSTEM_POWER_STATUS(ctypes.Structure):
    _fields_ = [
        ('ACLineStatus', wintypes.BYTE),
        ('BatteryFlag', wintypes.BYTE),
        ('BatteryLifePercent', wintypes.BYTE),
        ('Reserved1', wintypes.BYTE),
        ('BatteryLifeTime', wintypes.DWORD),
        ('BatteryFullLifeTime', wintypes.DWORD),
    ]
SYSTEM_POWER_STATUS_P = ctypes.POINTER(SYSTEM_POWER_STATUS)
GetSystemPowerStatus = ctypes.windll.kernel32.GetSystemPowerStatus
GetSystemPowerStatus.argtypes = [SYSTEM_POWER_STATUS_P]
GetSystemPowerStatus.restype = wintypes.BOOL
status = SYSTEM_POWER_STATUS()
if not GetSystemPowerStatus(ctypes.pointer(status)):
    raise ctypes.WinError()
print('ACLineStatus', status.ACLineStatus)
print('BatteryFlag', status.BatteryFlag)
print('BatteryLifePercent', status.BatteryLifePercent)
print('BatteryLifeTime', status.BatteryLifeTime)
print('BatteryFullLifeTime', status.BatteryFullLifeTime)
On my system that prints this (basically meaning "desktop, plugged in"):
ACLineStatus 1
BatteryFlag -128
BatteryLifePercent -1
BatteryLifeTime 4294967295
BatteryFullLifeTime 4294967295