I was having this problem, when I was calling a soap method to obtain my data, and then return a json string, when I tried to do json_decode I just keep getting null.
Since I was using nusoap to do the soap call I tried to just return json string and now I could do a json_decode, since I really neaded to get my data with a SOAP call, what I did was add ob_start() before include nusoap, id did my call genereate json string, and then before returning my json string I did ob_end_clean(), and GOT MY PROBLEM FIXED :)
EXAMPLE
//HRT - SIGNED
//20130116
//verifica se um num assoc deco é valido
ob_start();
require('/nusoap.php');
$aResponse['SimpleIsMemberResult']['IsMember'] = FALSE;
if(!empty($iNumAssociadoTmp))
{
    try
    {
        $client = new soapclientNusoap(PartnerService.svc?wsdl',
         array( 
            // OPTS 
            'trace' => 0,
            'exceptions' => false,
            'cache_wsdl' => WSDL_CACHE_NONE
         )
        );
    //MENSAGEM A ENVIAR
    $sMensagem1 = '
        <SimpleIsMember>
            <request>
                <CheckDigit>'.$iCheckDigitAssociado.'</CheckDigit>
                <Country>Portugal</Country>
                <MemberNumber">'.$iNumAssociadoDeco.'</MemberNumber>
            </request>
        </SimpleIsMember>';
    $aResponse = $client->call('SimpleIsMember',$sMensagem1);
    $aData = array('dados'=>$aResponse->xpto, 'success'=>$aResponse->example);
    }
}
ob_end_clean();
return json_encode($aData);