*.psd1 files contain PowerShell hashtable literals and therefore require the same syntax as when defining such literals in code:
Therefore, if you want to create an entry with key path that contains the string literal ./python/buildzig.py (or ./powershell/msterminal.ps1), you must quote it - either form is OK here:
path = '.\powershell\msterminal.ps1'
path = ".\powershell\msterminal.ps1"
However, given that in the context of a *.psd1 file you're virtually limited to literal values, use of '...' (single quotes) makes more sense (see about_Quoting_Rules).
As for what you tried:
A hashtable entry such as path = ./python/buildzig.py attempts to create an entry with key path and the value that is the result of executing file ./python/buildzig.py, because - in the absence of quoting - the token is interpreted as a command (see about_Parsing to learn about how PowerShell parses commands and expressions).
The - unfortunately vague - error message you saw (Cannot generate a PowerShell object for a ScriptBlock evaluating dynamic expressions.), stems from the fact that for security reasons, executing commands isn't permitted in *.psd1 files, which are (mostly[1]) limited to defining literal values.
[1] You can use the following "variables", which in effect are constants: $true, $false, $null. Additionally, depending on the purpose of the *.psd1 file, a select few additional automatic variables are permitted: $PSCulture and $PSUICulture, except in files to be read by Import-PowerShellDataFile, and, additionally, $PSScriptRoot, $PSEdition, and $EnabledExperimentalFeatures in module manifests - see about_Language_Modes.