A-level Chemistry/WJEC/Module 2/Alcohols and acids

HalogenoAlkane Production (Nucleophilic substitution)


Reactants: An alcohol (e.g. ethanol), a hydrogen halide (e.g. HBr)
Products: a HalogenoAlkane (e.g. bromoethane), water
Conditions: no special
C2H5OH + HBr → C2H5Br + H2O

Oxidation

Conditions: Acidified Potassium Dichromate(VI) or Sodium Dichromate(VI) is used as an oxidising agent. Reaction occurs in reflux.

The products that form from oxidation depend on the structure of the alcohol.

The oxidation of the primary alcohol, ethanol with Cr2O72- / H+ is as follows: CH3CH2OH + [O] → CH3CHO (the aldehyde; ethanal)

Remember: Oxidation is defined as the gain of Oxygen AND/OR the loss of hydrogen.


Primary alcohols: oxidise to aldehydes and then to carboxylic acids
Secondary alcohols: Oxidise to ketones
Tertiary alcohols: Cannot be oxidised

Combustion

(Complete) Combustion of any alcohol produces carbon dioxide and water.
Burning completely in an excess of oxygen
C2H5OH + 3 O2 → 2 CO2 + 3 H2O

However, incomplete combustion can occur when oxygen is not in excess (lack of oxygen) which can cause carbon monoxide (CO) or even carbon residue (C) to form as the products.

Esterification

Remember the basic principle:

ACID + ALCOHOL → ESTER + WATER

An alcohol (e.g. ethanol) + a carboxylic acid (e.g. ethanoic acid) → an ester (e.g. ethyl ethanoate) and water
Conditions: H2SO4 (sulfuric acid) Catalyst

Dehydration

Reactants: An alcohol
Products: Alkene + water
Conditions: hot and concentrated sulfuric acid

An alcohol can be formed by the hydration of the alkene; ethene, shown below:
CH2=CH2(g) + H2O(g) → CH3CH2OH(g)
Conditions: 300 degrees Celsius
60 atm pressure
H3PO4 (phosphoric acid) catalyst.