JSON (or YAML, or whatever) serialisation is probably better, but if you're already writing the dictionary to a text file in python syntax, complete with a variable name binding, you could just write that to a .py file instead. Then that python file would be importable and usable as is. There's no need for the "function which returns a dictionary"  approach, since you can directly use it as a global in that file. e.g.
# generated.py
please_dont_use_dict_as_a_variable_name = {'Adam': 'Room 430', 'Bob': 'Room 404'}
rather than:
# manually_copied.py
def get_dict():
    return {'Adam': 'Room 430', 'Bob': 'Room 404'}
The only difference is that manually_copied.get_dict gives you a fresh copy of the dictionary every time, whereas generated.please_dont_use_dict_as_a_variable_name[1] is a single shared object. This may matter if you're modifying the dictionary in your program after retrieving it, but you can always use copy.copy or copy.deepcopy to create a new copy if you need to modify one independently of the others.
[1] dict, list, str, int, map, etc are generally viewed as bad variable names. The reason is that these are already defined as built-ins, and are used very commonly. So if you give something a name like that, at the least it's going to cause cognitive-dissonance for people reading your code (including you after you've been away for a while) as they have to keep in mind that "dict doesn't mean what it normally does here". It's also quite likely that at some point you'll get an infuriating-to-solve bug reporting that dict objects aren't callable (or something), because some piece of code is trying to use the type dict, but is getting the dictionary object you bound to the name dict instead.