In order to tokenize you can use the String.split() with a single space as a separator;
String[] inputs = input.split(" ");
Here is a full solution that I've just written that which uses a Stack implementation based on a singly linked list in order to make a postfix calculator;
A - PostFixCalculator
import java.io.BufferedReader;
import java.io.FileReader;
import java.io.IOException;
public class PostFixCalculator {
    private static final String ADD = "+"; 
    private static final String SUB = "-";
    private static final String MUL = "*";
    private static final String DIV = "/";
    public void calculateFile(String fileName) throws IOException {
        BufferedReader br = null;
        StringBuilder sb = null;
        try {
            FileReader fileReader = new FileReader(fileName);
            br = new BufferedReader(fileReader);
            sb = new StringBuilder();
            String line = br.readLine();
            while (line != null) {
                sb.append(line);
                line = br.readLine();
            }
            String input = sb.toString();
            System.out.println(input + " = " + calculate(input));
        } catch (IOException e) {
            e.printStackTrace();
        } finally {
            br.close();
        }
    }
    private int calculate(String input) {
        SinglyLinkedListStack<Integer> stack = new SinglyLinkedListStack<>();
        String[] inputs = input.split(" ");
        return handleCalculation(stack, inputs);
    }
    private static int handleCalculation(SinglyLinkedListStack<Integer> stack, String[] el) {
        int operand1, operand2;
        for(int i = 0; i < el.length; i++) {
            if( el[i].equals(ADD) || el[i].equals(SUB) || el[i].equals(MUL) || el[i].equals(DIV) ) {
                operand2 = stack.pop();
                operand1 = stack.pop();
                switch(el[i]) {
                    case ADD: {
                        int local = operand1 + operand2;
                        stack.push(local);
                        break;
                    }
                    case SUB: {
                        int local = operand1 - operand2;
                        stack.push(local);
                        break;
                    }
                    case MUL: {
                        int local = operand1 * operand2;
                        stack.push(local);
                        break;
                    }
                    case DIV: {
                        int local = operand1 / operand2;
                        stack.push(local);
                        break;
                    }
                }
            } else {
                stack.push(Integer.parseInt(el[i]));
            }
        }
        return stack.pop();
    }
}
B - SinglyLinkedListStack
public class SinglyLinkedListStack<T> {
    private int size;
    private Node<T> head;
    public SinglyLinkedListStack() {
        head = null;
        size = 0;
    }
    public void push(T element) {
        if(head == null) {
            head = new Node(element);
        } else {
            Node<T> newNode = new Node(element);
            newNode.next = head;
            head = newNode;
        }
        size++;
    }
    public T pop() {
        if(head == null)
            return null;
        else {
            T topData = head.data;
            head = head.next;
            size--;
            return topData;
        }
    }
    public T top() {
        if(head != null)
            return head.data;
        else
            return null;
    }
    public int size() {
        return size;
    }
    public boolean isEmpty() {
        return size == 0;
    }
    private class Node<T> {
        private T data;
        private Node<T> next;
        public Node(T data) {
            this.data = data;
        }
    }
}
C - Demo
import java.io.IOException;
public class PostFixCalculatorDemo {
    public static void main(String[] args) throws IOException {
        PostFixCalculator calc = new PostFixCalculator();
        calc.calculateFile("postfix.txt");
    }
}
D - Sample Input File: "postfix.txt"
6 5 2 3 + 8 * + 3 + * 
E - Demo Output
6 5 2 3 + 8 * + 3 + *  = 288