One approach is to create a bitmask, and then right-shift the value.
That is, create a bitmask so that your integer is '1000....' or '0.....' - depending on whether that first bit is a 0 or a 1.
Then take that integer and right-shift it until it becomes the least-significant-bit, rather than the most-significant. As an example, 0b10000000 >> 8 is 1.
So first, depending on the size of your integer, you have to shift, well, however many bits are relevant.
Then you have to create the bitmask. Let's just take a 1-byte integer:
unsigned int i = 1 << 8 would create an integer i whose most significant bit is a 1.
Or you could use hex. You already know that 0xFF == 11111111. You can actually break it up further: 0xF0 == 11110000
Since 0xF == 1111 in binary, well, we will do the reverse. 1000 in binary is what, in hex? 1000 in binary is the number 8, which also happens to equal 0x8
So, for a single byte, the mask for the leftmost bit is 0x80.
Now! Apply this to 32 bits!
Good luck!