@ManyToOne associated with @BatchSize could make sense only if the corresponding field is marked as lazy (lazy=true).
Indeed, if the field is not lazy, it's by definition already loaded since the enclosing entity is loaded, so the problem of database calls doesn't apply.
Imagine a Person class who has a collection of ShoesPair element (ShoesPair.class) and within this one is present an owner field marked as lazy (since optional and not really bringing an important information when retrieving a specific pair of shoes).
One wants to iterate through 25 pair of shoes (25 ShoesPair objects) in order to retrieve their owner.
If the owner field (corresponding to one person) is only annotated with @ManyToOne, there would be 25 select to database.
However, if annoted with @BatchSize(size=5), there would be merely 5 calls and so increasing performance.
From the Hibernate documentation, it is precised that batch size does not only apply with collections:
You can also enable batch fetching of collections.
Hibenate mentions especially @OneToMany cases, because these one are applied with fields that are in 90% of cases marked as lazy.