Just use datetime.time.min and datetime.time.max:
>>> import datetime
>>> datetime.time.min
datetime.time(0, 0)
>>> datetime.time.max
datetime.time(23, 59, 59, 999999)
You can combine that with a datetime.date instance to get a full datetime.datetime instance:
>>> datetime.datetime.combine(datetime.date.today(), datetime.time.max)
datetime.datetime(2012, 12, 1, 23, 59, 59, 999999)
To re-use an existing datetime.datetime instance, use the .combine() method together with the .date() method on the datetime.datetime instance to create a new datetime.datetime instance:
>>> datetime.datetime.combine(datetime.datetime.now().date(), datetime.time.min)
datetime.datetime(2012, 12, 1, 0, 0)
To get a series of dates, use datetime.timedelta instances to create offsets. A series of dates relative to today is then easy:
today = datetime.date.today()
lastweek = today - datetime.timedelta(days=7)
for i in range(7):
    aday = lastweek + datetime.timedelta(days=i)
    first = datetime.datetime.combine(aday, datetime.time.min)
    last = datetime.datetime.combine(aday, datetime.time.max)
    print first, last