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I programmed assembly on a Mac.  It was Motorola 680x0 assembler using MPW.  I've touched on the PowerPC assembler a few times in CodeWarrior and ProjectBuilder.  Now ProjectBuilder is called XCode, and there is Intel.  The assembler is one of the many tools within XCode.
I originally learned assembler on the Apple II:  the 6502 machine language monitor built in ROM, the Sweet16 mini-assembler, and others.  Later, I used Intel 80186 assembler to speed up slow bits of C code, and work paid for a one day course on Intel 80186 assembler at a university.  Later, I had to maintain some 680x0 assembly for the Mac.  That was a long time ago.
I don't think there is any reason not to do assembly.  Learning is great.  Learn all you can.  Drop into a low enough level debugger and look at the disassembled code.
My advice is: 
Don't be scared.