The question is tagged with ubuntu, but the solution of un-commenting the extension=mysqli.dll is specific to windows. I am confused here?!, anyways, first thing run <? php phpinfo ?> and search for mysql* under Configuration heading. If you don't see such a thing implies you have not installed or enabled php-mysql. So first install php-mysql
sudo apt get install php-mysql
This command will install php-mysql depending on the php you have already installed, so no worries about the version!!.
Then comes the unix specific solution, in the php.ini file un-comment the line
extension=msql.so
verify that msql.so is present in /usr/lib/php/<timestamp_folder>,
ELSE
extension=path/to/msql.so
Then finally restart the apache and mysql services, and you should now see the mysql section under Configrations heading in phpinfo page