I have no idea how a file in ASCII encoding could contain Chinese data but if it were possible this would be the command:
iconv -f ASCII -t BIG5 asciifile -o big5file.txt
It will convert your file in ASCII encoding to BIG5 and write the output to big5file.txt.
But most likely it is not ASCII that you have in the original file. Make sure you detect the exact encoding and then use it in the command. Use iconv -l to view all available encodings.
You can try to figure out the real encoding with chardet or cchardet. If not available in your terminal, you can install it with pip install chardet (or pip install cchardet).
Once installed pass the the file name as first argument:
chardet Tian.Jiang.Xiong.Shi.srt
>>> Tian.Jiang.Xiong.Shi.srt: GB2312 with confidence 0.99
If you install with pip3 then the script name will be chardet3 or chardetect3.