In C, the literal “5.9” has type double and is converted by common compilers to 5.9000000000000003552713678800500929355621337890625, because they use binary IEEE-754 floating point, and that number is the value representable as a double that is closest to 5.9. Your code initializes a float with that value. That requires converting a double to a float, and the result is 5.900000095367431640625, because that is the float value that is closest to the double value. Obviously, the latter is greater than the former, which is why your output is “Greater than”.
With .9, the literal “.9” is converted to the double 0.90000000000000002220446049250313080847263336181640625. Then that double is converted to the float 0.89999997615814208984375, which is obviously less than the double.