Unfortunately there's no standard way to get objects aligned like that.  There's almost always some compiler-specific trick, such as __attribute__ in GCC, but you'll have to check your compiler's documentation.
(Of course there's no standard use for that kind of alignment either, which is why there's no standard method for achieving it.  So you're probably resorting to extensions already, so there's no real harm going further.)
A union that contains a large-enough elemental object often does the trick, but I believe the largest elemental C objects for MIPS CPUs are long long and double, which are only 8 bytes.