I have a DataFrame that looks like (it's a set of combinations):
   A  B  C  
a  1  1  3  
b  1  2  4  
c  2  1  5  
d  2  2  6  
Which I would like to transform into a matrix where the new columns and indexes are unique values of two of the columns (A and B) and the cells are the join between these two unique values from a third column (C).
With A as the index, B as the columns and C as the cell values I would have something like:
   B
A  1 2
1  3 4  
2  5 6
To generate this new 'matrix' DataFrame I iteratively filter the original DF by the unique values in columns A, then get the C column as a Series, like:
for ind in unique_indexes: # made by using .drop_duplicates on the column
    rows = original_table[(original_table['A'] == ind)] 
    new_series = rows['C']
I'm then trying to glue all of these Series together as rows in a new DataFrame, but can't get any of them to either append or concat into the new DataFrame (following both the docs or similar questions on SO), e.g. 
# with suitable placement in 'for' loop
df = DataFrame()
df.append(new_series)
>>> print df
Empty DataFrame
Is there a) a better way of doing this transformation, or b) a step that I'm missing in appending series to a DataFrame?
Cheers
 
     
    