Something does happen, it just isn't noticeable
Python runs scripts from top to bottom. def is a statement, and it executes when it is encountered, just like any other statement. However, the effect of this is to create the function (and assign it a name), not to call it. Similarly, import is a statement that loads the other module (and makes its code run top to bottom, with its own global-variable context), and assigns it a name.
When the example code runs, therefore, three things happen:
- The code for the - sysstandard library module runs, and then the name- sysin our own module's global variables is bound to that module
 
- A function is created from the code for - random, and then the name- randomis bound to that function
 
- A function is created from the code for - main, and then the name- mainis bound to that function
 
There is nothing to call the functions, so they aren't called. Since they aren't called, the code inside them isn't run - it's only used to create the functions. Since that code doesn't run, the file isn't read and nothing is printed.
There are no "special" function names
Unlike in some other languages, Python does not care that a function is named main, or anything else. It will not be run automatically.
As the Zen of Python says, "Explicit is better than implicit". If we want a function to be called, we have to call it. The only things that run automatically are the things at top level, because those are the instructions we explicitly gave.
The script starts at the top
In many real-world scripts, you may see a line that says if __name__ == '__main__':. This is not "where the script starts". The script runs top to bottom.
Please read What does if __name__ == "__main__": do? to understand the purpose of such an if statement (short version: it makes sure that part of your top-level code is skipped if someone else imports this file as a module). It is not mandatory, and it does not have any kind of special "signalling" purpose to say where the code starts running. It is just a perfectly normal if statement, that is checking a slightly unusual condition. Nothing requires you to use it in a script (aside from wanting to check what it checks), and nothing prevents you from using it more than once. Nothing prevents you from checking whether __name__ is equal to other values, either (it's just... almost certainly useless).