I'm working with a dataset in R that has missing observations in my vectorFirstOfHCPCS.Code.  I want to code those NAs/HCPC codes based on the value in another vector, FirstOfService.Description.  Not every NA will be filled with the same value, but rather there are 6 possible values the NA could be coded as.  I tried running a loop to fill in the NAs, but I think because I don't have EVERY FirstOfService.Description listed in the loop, R doesn't know what to do with those values.  Here is my code for the loop and the resulting error (updated with canary's suggestion):
    for (i in 1:248308){
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("State Mental Retardation Facility - Inpatient (ICF/MR) PT65",
      "Local Psychiatric Hospital/IMD PT68", "Local Psychiatric Hospital - Acute Community PT73","State Psychiatric Hospital - Inpatient PT22"))
{Master$FirstOfHCPCS.Code[i]=2}
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("Inpatient Hospital Ancillary Services - Room and Board",
      "Inpatient Hospital Ancillary Services - Leave of Absence",
      "Inpatient Hospital Ancillary Services - Pharmacy",
      "Inpatient Hospital Ancillary Services - Medical/Surgical Supplies and Devices",
      "Inpatient Hospital Ancillary Services - Laboratory",
      "Inpatient Hospital Ancillary Services -EKG/ECG",
      "Inpatient Hospital Ancillary Services - EEG",
      "Inpatient Hospital Ancillary Services - Psychiatric/Psychological Treatments/Services",
      "Inpatient Hospital Ancillary Services - Other Diagnosis Services",
      "Inpatient Hospital Ancillary Services - Other Therapeutic Services"=="Inpatient Hospital Ancillary Services - Radiology",
      "Inpatient Hospital Ancillary Services - Respiratory Services",
      "Inpatient Hospital Ancillary Services -Physical Therapy",
      "Inpatient Hospital Ancillary Services - Occupational Therapy",
      "Inpatient Hospital Ancillary Services - Speech-Language Pathology",
      "Inpatient Hospital Ancillary Services - Emergency Room",
      "Inpatient Hospital Ancillary Services - Pulmonary Function",
      "Inpatient Hospital Ancillary Services - Audiology",
      "Inpatient Hospital Ancillary Services - Magnetic Resonance Technology (MRT)",
      "Inpatient Hospital Ancillary Services - Pharmacy",
      "Additional Codes-ECT Facility Charge")){Master$FirstOfHCPCS.Code[i]=1}
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("Pharmacy (Drugs and Other Biologicals)")){Master$FirstOfHCPCS.Code[i]=3}
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("Crisis Observation Care")){Master$FirstOfHCPCS.Code[i]=4}
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("Outpatient Partial Hospitalization")){Master$FirstOfHCPCS.Code[i]=5}
  if (is.na(Master$FirstOfHCPCS.Code[i])&Master$FirstOfService.Description[i]%in%c("Other")){Master$FirstOfHCPCS.Code[i]=6}}
Error in if (is.na(Master$FirstOfHCPCS.Code[i]) & Master$FirstOfService.Description[i] %in%  : 
  argument is of length zero
I also ran sum(is.na(Master$FirstOfHCPCS.Code)) to find out how many rows I have with NA and then replacing the 248308 in the loop code with that number (27186) but I still get the same error as above.  How do I fill the NAs with multiple values?  Thanks for your help!
Per Request, sample code and desired output (Desired_FirstOfHCPCS.Code)
   ##Sample Code##
FirstOfService.Description<-c("State Mental Retardation Facility - Inpatient (ICF/MR) PT65","Wraparound", "Inpatient Hospital Ancillary Services - Room and Board",
                              "Pharmacy (Drugs and Other Biologicals)","Local Psychiatric Hospital - Acute Community PT73","State Psychiatric Hospital - Inpatient PT22","Case Management","Crisis Observation Care","Outpatient Partial Hospitalization",
                              "Other")
Desired_FirstOfHCPCS.Code<-c(2, 85, 1, 3, 2, 2, 11, 4, 5, 6)
FirstOfHCPCS.Code<-c(NA, 85, NA, NA, NA, NA, 11, NA, NA, NA)
df<-data.frame(FirstOfService.Description, FirstOfHCPCS.Code)
df
Output:
                                    FirstOfService.Description FirstOfHCPCS.Code
1  State Mental Retardation Facility - Inpatient (ICF/MR) PT65                NA
2                                                   Wraparound                85
3       Inpatient Hospital Ancillary Services - Room and Board                NA
4                       Pharmacy (Drugs and Other Biologicals)                NA
5            Local Psychiatric Hospital - Acute Community PT73                NA
6                  State Psychiatric Hospital - Inpatient PT22                NA
7                                              Case Management                11
8                                      Crisis Observation Care                NA
9                           Outpatient Partial Hospitalization                NA
10                                                       Other                NA
What I want it to look like:
#Desired Output
df2<-data.frame(FirstOfService.Description, Desired_FirstOfHCPCS.Code)
df2
                                    FirstOfService.Description Desired_FirstOfHCPCS.Code
1  State Mental Retardation Facility - Inpatient (ICF/MR) PT65                         2
2                                                   Wraparound                        85
3       Inpatient Hospital Ancillary Services - Room and Board                         1
4                       Pharmacy (Drugs and Other Biologicals)                         3
5            Local Psychiatric Hospital - Acute Community PT73                         2
6                  State Psychiatric Hospital - Inpatient PT22                         2
7                                              Case Management                        11
8                                      Crisis Observation Care                         4
9                           Outpatient Partial Hospitalization                         5
10                                                       Other                         6
 
    