On the Global.asax page just add the below code
 void Application_Error(object sender, EventArgs e) 
   { 
        // Code that runs when an unhandled error occurs
        // Get the error details 
        HttpException lastErrorWrapper = Server.GetLastError() as HttpException;
        Exception lastError = lastErrorWrapper;
        if (lastErrorWrapper.InnerException != null)
            lastError = lastErrorWrapper.InnerException;
        string lastErrorTypeName = lastError.GetType().ToString();
        string lastErrorMessage = lastError.Message;
        string lastErrorStackTrace = lastError.StackTrace;
        const string ToAddress = "youremail@yourdomain.com";
        const string FromAddress = "noreply@yourdomain.com";
        const string Subject = "An Error Has Occurred on Application Name!";
        // Create the MailMessage object 
        MailMessage msg = new MailMessage();
        string[] eAddresses = ToAddress.Split(';');
        for (int i = 0; i < eAddresses.Length; i++)
        {
            if (eAddresses[i].Trim() != "")
            {
                msg.To.Add(new MailAddress(eAddresses[i]));
            }
        }
        msg.From = (new MailAddress(FromAddress));
        msg.Subject = Subject;
        msg.IsBodyHtml = true;
        msg.Priority = MailPriority.High;
        msg.Body = string.Format(@" 
<html> 
<body> 
  <h1>An Error Has Occurred!</h1> 
  <table cellpadding=""5"" cellspacing=""0"" border=""1""> 
  <tr> 
  <td text-align: right;font-weight: bold"">URL:</td> 
  <td>{0}</td> 
  </tr> 
  <tr> 
  <td text-align: right;font-weight: bold"">User:</td> 
  <td>{1}</td> 
  </tr> 
  <tr> 
  <td text-align: right;font-weight: bold"">Exception Type:</td> 
  <td>{2}</td> 
  </tr> 
  <tr> 
  <td text-align: right;font-weight: bold"">Message:</td> 
  <td>{3}</td> 
  </tr> 
  <tr> 
  <td text-align: right;font-weight: bold"">Stack Trace:</td> 
  <td>{4}</td> 
  </tr>  
  </table> 
</body> 
</html>",
            Request.Url,
            Request.ServerVariables["LOGON_USER"],
            lastErrorTypeName,
            lastErrorMessage,
            lastErrorStackTrace.Replace(Environment.NewLine, "<br />"));
        // Attach the Yellow Screen of Death for this error    
        string YSODmarkup = lastErrorWrapper.GetHtmlErrorMessage();
        if (!string.IsNullOrEmpty(YSODmarkup))
        {
            Attachment YSOD = Attachment.CreateAttachmentFromString(YSODmarkup, "YSOD.htm");
            msg.Attachments.Add(YSOD);
        }
        // Send the email 
        SmtpClient smtp = new SmtpClient();
        smtp.Send(msg);
        Server.Transfer("/Error.aspx");
    }