First stackoverflow post, so please forgive if I'm missing something obvious. I did search for an answer first but didn't find one I recognized as relevant.
In this jsfiddle, I have a div that I'm using as a hover target to get some transitions to happen to an <a> element. 
http://jsfiddle.net/ramatsu/Q9rfg/
Here's the markup:
<div class="target">Target
  <a href="#" class="LightMe"><p>.LightMe</p></a>
</div>
And the css:
body {
  background-color: #099;
  height: 100%;
  width: 100%;
  margin-top:200px;
}
.target{
  position: absolute;
  left: 40%;
  height: 100px;
  width: 200px;
  padding: 20px;
  background-color: #ccc;
  cursor: pointer;
 }
a {
  display: block;
  position: relative;
  padding: 1px;
  border-radius: 15%;
}
a.LightMe {
  /*Starting state */
    background-color: white;
    border-style:solid;
    border-color:#fff;
    top: -120px;
    left: -200px;
    height: 80px;
    width: 80px;
    z-index: 10;
    opacity: 0;
    transition:left 0.55s  ease, opacity .5s .7s ease;
    -webkit-transition:left 0.55s  ease, opacity .5s .7s ease;
    -o-transition:left 0.55s  ease, opacity .5s .7s ease;
}
.target:hover a.LightMe {
/*Ending state*/
  left: 80px;
  opacity: 1;
  transition:left 0.55s .7s ease, opacity .5s ease;
  -webkit-transition:left 0.55s .7s ease, opacity .5s ease;
  -o-transition:left 0.55s .7s ease, opacity .5s ease;
}
.target:hover {
    transition: background-color 500ms ease;
    -webkit-background-color 500ms ease;
    -o-background-color 500ms ease;
    background-color:#999;
}
- Hover over the grey box labeled Target and back off again to see the transitions on the <a>element. It's doing what I want: opacity fades in during position delay, then it slides to the desired position. when moving out of the hover target, the<a>slides to it's original position, then opacity fades back out. All good so far.
- The catch is, if the user hovers over the hidden <a>element, it triggers the same set of transitions, which causes all kinds of unintended havoc.
I'd like to prevent any response to a hover directly over the <a> element, and really like to continue to keep it in css if possible.
I tried adding an explicit hover to <a> and .LightMe to override this, to no avail. (Though that could be that I just didn't get the selector syntax right.)
I added the background-color transition to .target intentionally for testing, and it provided an interesting clue: hovering over the <a> triggers the upstream transitions of the .target div. That's about where my brain broke and I decided I'd better seek help.
I'm working with a few things here that are above my head, I just started from the closest thing I could find and worked toward what I needed. This was the starting point jsfiddle (with thanks to the author):
 
     
    