When you declare int *ptr, you're creating a variable called ptr which can hold the address of an int. When you dereference it in *ptr = 5, you're saying "store 5 in the address that ptr points to" - but as ptr is uninitialised, where it points to is undefined. So you're invoking undefined behaviour.
An int * does not store an int, but just an address that points to one. There still has to be a real int at that address.
If you want to allocate an int that exists outside of the local scope, you can use malloc. A simple conversion of your example without error checking:
int *ptr = malloc(sizeof(int));
*ptr = 5;
printf(" %d\n",*ptr);
If you do use malloc, just remember to free the allocated memory when you're finished:
free(ptr);