I think what you want is this:
ASP.NET MVC1
Html.ActionLink(article.Title, 
                "Login",  // <-- Controller Name.
                "Item",   // <-- ActionMethod
                new { id = article.ArticleID }, // <-- Route arguments.
                null  // <-- htmlArguments .. which are none. You need this value
                      //     otherwise you call the WRONG method ...
                      //     (refer to comments, below).
                )
This uses the following method ActionLink signature:
public static string ActionLink(this HtmlHelper htmlHelper, 
                                string linkText,
                                string controllerName,
                                string actionName,
                                object values, 
                                object htmlAttributes)
ASP.NET MVC2
two arguments have been switched around
Html.ActionLink(article.Title, 
                "Item",   // <-- ActionMethod
                "Login",  // <-- Controller Name.
                new { id = article.ArticleID }, // <-- Route arguments.
                null  // <-- htmlArguments .. which are none. You need this value
                      //     otherwise you call the WRONG method ...
                      //     (refer to comments, below).
                )
This uses the following method ActionLink signature:
public static string ActionLink(this HtmlHelper htmlHelper, 
                                string linkText,
                                string actionName,
                                string controllerName,
                                object values, 
                                object htmlAttributes)
ASP.NET MVC3+
arguments are in the same order as MVC2, however the id value is no longer required:
Html.ActionLink(article.Title, 
                "Item",   // <-- ActionMethod
                "Login",  // <-- Controller Name.
                new { article.ArticleID }, // <-- Route arguments.
                null  // <-- htmlArguments .. which are none. You need this value
                      //     otherwise you call the WRONG method ...
                      //     (refer to comments, below).
                )
This avoids hard-coding any routing logic into the link.
 <a href="/Item/Login/5">Title</a> 
This will give you the following html output, assuming:
- article.Title = "Title"
- article.ArticleID = 5
- you still have the following route defined
.
.
routes.MapRoute(
    "Default",     // Route name
    "{controller}/{action}/{id}",                           // URL with parameters
    new { controller = "Home", action = "Index", id = "" }  // Parameter defaults
);