long a2 = 100L * 1024 * 1024 * 1024;
In this operation however at least one operand is long. hence  the  operation  is  carried  out  using  64-bit  precision,  and  the  result  of the numerical operator is of type long. The other non-long operand are
widened to type long by numeric promotion and resulted value gets stored to to variable a2.
 long a1 = 100 * 1024 * 1024 * 1024;
The constant expression of plain integer, the result of the expression was computed as a type int. The computed value however too large to fit in an integer and hence overflowed, resulting in 0 and gets stored to a1 variable.  
Edit: As is asked in the following comment:
Why doesn't it go negative?
Because while in integer computation the second computation is equivalent to 25 * 2^32 where ^ has the power meaning and 2^32 integer value is 0. However, to explain why it's value is 0: In binary:
 100 * 1024 * 1024 * 1024 == 25 * 2^32;
 Integer.MAX_VALUE =  2 ^ 31 -1 = 0 11111111 11111111 11111111 1111111
 Integer.MAX_VALUE + 1 = 2 ^ 31 = 1 00000000 00000000 00000000 0000000 
2 ^ 31 is a negative integer(-2147483648) as the sign bit is 1 And hence 2 ^ 32 is just a multiplication of 2 to 2 ^ 31: a left shift and the sign bit will become 0 and hence the result is 0.    
Check out the java language specification: 4.2.2: Integer operation for details.