There are many, many bad ideas in the following code:
package supersuper;
import static java.lang.System.out;
interface Human {
    String x();
}
class Person implements Human {
    public String designation;  //bad idea
    Person() {
        designation = x();
    }
    @Override
    public String x() {
        return "Person";
    }
}
class Student extends Person {
    Student() {
        super();
    }
    @Override
    public String x() {
        return "Student";
    }
}
class TeachingAssistant extends Student {
    TeachingAssistant() {
        super();
    }
}
public class SuperSuper {
    public static void main(String[] args) {
        TeachingAssistant ta = new TeachingAssistant();
        out.println(ta.designation);
    }
}
dunno what you want, really.  Post some code as a starting point for some context.  But, no, you cannot invoke super.super.x() as per the comments.
I only present this to you get you started to refine your question.