You should do three things differently compared to working code that I have, this may or may not solve your actual problem:
1) You should not pass cmd, with Runtime.getRuntime().exec() you are essentially in the commandline interface already.
2) You should enclose every argument with spaces within quotes, so in Java it looks like the following: "\"argument with spaces\"".
3) There may only be one argument in each element, in this case in String[].
In your code you may do it like this:
p = Runtime.getRuntime().exec(new String[]{
"\"C:/OpenOffice 4/program/python.exe\"",
"\"C:/OpenOffice 4/program/DocumentConverter.py\"",
"\"C:/OpenOffice 4/program/a.odt\"",
"\"C:/OpenOffice 4/program/b.pdf\""});
Then at a later point you can call p.waitFor() if you want your thread (program) to waiit until the execution has finished.