As best as I can vaguely guess from the limited information provided, in this query:
"SELECT name,age,dob,address FROM TABLENAME WHERE pmrn=%s" % (self.pmrn)
you appear to be doing a string substitution of a value into a query.
First, this is dangerously wrong, and you should never ever do it without an extremely good reason. Always use parameterized queries. psycopg2 supports these, so there's no excuse not to. So do all the other Python interfaces for PostgreSQL, but I'm assuming you're using psycopg2 because basically everyone does, so go read the usage documentation to see how to pass query parameters.
Second, as a result of failing to use parameterized queries, you aren't getting any help from the database driver with datatype handling. You mentioned that pmrn is of type char - for which I assume you really meant varchar; if it's actually char then the database designers need to be taken aside for a firm talking-to. Anyway, if you substitute an unquoted number in there your query is going to look like:
pmrn = 201401270001
and if pmrn is varchar that'll be an error, because you can't compare a text type to a number directly. You must pass the value as text. The simplistic way is to put quotes around it:
pmrn = '201401270001'
but what you should be doing instead is letting psycopg2 take care of all this for you by using parameterized queries. E.g.
curs.execute("SELECT name,age,dob,address FROM TABLENAME WHERE pmrn=%s", (self.pmrn,))
i.e. pass the SQL query as a string, then a 1-tuple containing the query params. (You might have to convert self.pmrn to str if it's an int, too, eg str(self.pmrn)).