Ok, here is how you do this with a full working example.
Html
This includes your invalid/duplicate id html which you have no control over         
var html = @"<h3>
            <div id='lib_presta'>
                Chambre standard 1 pers du <span class=''>03/03/2014</span>  au <span class=''>05/03/2014 </span>
            </div>
            <div id='prix_presta'>
                127.76 €
            </div>
        </h3><h3>
            <div id='lib_presta'>
                Chambre standard 2 pers du <span class=''>03/03/2014</span>  au <span class=''>05/03/2014 </span>
            </div>
            <div id='prix_presta'>
                227.76 €
            </div>
        </h3>";
C# Code
This loads the dom elements by their id's into two lists of descriptions and prices.
It then projects them into a list of HotelAvailability objects using the key values of both collections as the HotelName and Price properties.
        CQ dom = html;
        var libs = dom["#lib_presta"];
        var prixs = dom["#prix_presta"];
        var list = libs.Zip(prixs, (k, v) => new { k, v })
          .Select(h => new HotelAvailablity { HotelName = h.k.InnerText.Trim(), Price = h.v.InnerText.Trim() });

Run the above in a console app to test it.