Step debug into g++ 6.4 stdlibc++ source
Did you know that on Ubuntu's 16.04 default g++-6 package or a GCC 6.4 build from source you can step into the C++ library without any further setup?
By doing that we easily conclude that a Red-black tree used in this implementation.
This makes sense, since std::set can be traversed in order, which would not be efficient in if a hash map were used.
main.cpp
#include <cassert>
#include <set>
int main() {
    std::set<int> s;
    s.insert(1);
    s.insert(2);
    assert(s.find(1) != s.end());
    assert(s.find(2) != s.end());
    assert(s.find(3) == s3.end());
}
Compile and debug:
g++ -g -std=c++11 -O0 -o main.out main.cpp
gdb -ex 'start' -q --args main.out
Now, if you step into s.insert(1) you immediately reach /usr/include/c++/6/bits/stl_set.h:
487 #if __cplusplus >= 201103L
488       std::pair<iterator, bool>
489       insert(value_type&& __x)
490       {
491     std::pair<typename _Rep_type::iterator, bool> __p =
492       _M_t._M_insert_unique(std::move(__x));
493     return std::pair<iterator, bool>(__p.first, __p.second);
494       }
495 #endif
which clearly just forwards to _M_t._M_insert_unique.
So we open the source file in vim and find the definition of _M_t:
      typedef _Rb_tree<key_type, value_type, _Identity<value_type>,
           key_compare, _Key_alloc_type> _Rep_type;
       _Rep_type _M_t;  // Red-black tree representing set.
So _M_t is of type _Rep_type and _Rep_type is a _Rb_tree.
OK, now that is enough evidence for me. If you don't believe that _Rb_tree is a Black-red tree, step a bit further and read the algorithm.
unordered_set uses hash table
Same procedure, but replace set with unordered_set on the code.
This makes sense, since std::unordered_set cannot be traversed in order, so the standard library chose hash map instead of Red-black tree, since hash map has a better amortized insert time complexity.
Stepping into insert leads to /usr/include/c++/6/bits/unordered_set.h:
415       std::pair<iterator, bool>
416       insert(value_type&& __x)
417       { return _M_h.insert(std::move(__x)); }
So we open the source file in vim and search for _M_h:
      typedef __uset_hashtable<_Value, _Hash, _Pred, _Alloc>  _Hashtable;
      _Hashtable _M_h;
So hash table it is.
std::map and std::unordered_map
Analogous for std::set vs std:unordered_set: What data structure is inside std::map in C++?
Performance characteristics
You could also infer the data structure used by timing them:

Graph generation procedure and Heap vs BST analysis and at: Heap vs Binary Search Tree (BST)
We clearly see for: