What you're asking doesn't make any sense. The integer 0011 and the integer 11 are exactly the same number.*
If you want to format them as strings to print them out or to search a text file, you can do that with, e.g., format(n, '04'). It doesn't matter whether you're formatting 11 or 0011, they're both the same number, and that number will format to the string '0011'.
If you want to convert them to big-endian 32-bit C-style unsigned integers, again, they're both the same number, and struct.pack('>I', n) will pack that number to the byte string b'\x00\x00\x00\x0b'.
If you want to add them modulo 10000, again, they're both the same number, and (n + 9990) % 10000 will give you 1.
No matter what operation you dream up, there will be no difference.
* Actually, in Python 2.x, number literals starting with 0 are treated as octal, not decimal, so 0011 is actually 9, not 11. And in 3.x numbers starting with 0 are a SyntaxError, to avoid the confusion caused by accidentally writing octal numbers. But forget all that. We're not talking about the Python number literals, we're talking about something even simpler here: the numbers themselves.