Assuming that create_time contains the time the order was created, and you want the 100 clients with the latest orders, you can:
- add the create_time in your innermost query
- order the results of your outer query by the create_time desc
- add an outermost query that filters the first 100 rows using ROWNUM
Query: 
  SELECT * FROM (
     SELECT * FROM (
        SELECT 
          id, 
          client_id, 
          create_time,
          ROW_NUMBER() OVER(PARTITION BY client_id ORDER BY create_time DESC) rn 
        FROM order
      ) 
      WHERE rn=1
      ORDER BY create_time desc
  ) WHERE rownum <= 100
UPDATE for Oracle 12c
With release 12.1, Oracle introduced "real" Top-N queries. Using the new FETCH FIRST... syntax, you can also use:
  SELECT * FROM (
    SELECT 
      id, 
      client_id, 
      create_time,
      ROW_NUMBER() OVER(PARTITION BY client_id ORDER BY create_time DESC) rn 
    FROM order
  ) 
  WHERE rn = 1
  ORDER BY create_time desc
  FETCH FIRST 100 ROWS ONLY)