Why?
It's because of the implementation of qDebug().
From the source code:
inline QDebug &operator<<(QChar t) { stream->ts << '\'' << t << '\''; return maybeSpace(); }
inline QDebug &operator<<(const char* t) { stream->ts << QString::fromAscii(t); return maybeSpace(); }
inline QDebug &operator<<(const QString & t) { stream->ts << '\"' << t  << '\"'; return maybeSpace(); }
Therefore,
QChar a = 'H';
char b = 'H';
QString c = "Hello";
qDebug()<<a;
qDebug()<<b;
qDebug()<<c;
outputs
'H' 
 H 
"Hello"
Comment
So why Qt do this? Since qDebug is for the purpose of debugging, the inputs of various kinds of type will become text stream output through qDebug.
For example, qDebug print boolean value into text expression true / false:
inline QDebug &operator<<(bool t) { stream->ts << (t ? "true" : "false"); return maybeSpace(); }
It outputs true or false to your terminal. Therefore, if you had a QString which store true, you need a quote mark " to specify the type.