var item= (from t1 in _dbEntities.PurchaseSales
                join t2 in _dbEntities.ItemTypes on t1.ItemTypeID equals t2.ID
                where t2.ID.Equals(null)
               select t2).ToList();
how to do left join in it
    var item= (from t1 in _dbEntities.PurchaseSales
                join t2 in _dbEntities.ItemTypes on t1.ItemTypeID equals t2.ID
                where t2.ID.Equals(null)
               select t2).ToList();
how to do left join in it
Use DefaultIfEmpty:
var item= (from t1 in _dbEntities.PurchaseSales
                join t2 in _dbEntities.ItemTypes on t1.ItemTypeID equals t2.ID into t
                from l in t.DefaultIfEmpty()
                where l == null
               select t1).ToList();