I've written simple server using Owin Self-hosting and WebApi:
namespace OwinSelfHostingTest
{
    using System.Threading;
    using System.Web.Http;
    using Microsoft.Owin.Hosting;
    using Owin;
    public class Startup
    {
        public void Configuration(IAppBuilder builder)
        {
            var config = new HttpConfiguration();
            config.Routes.MapHttpRoute(
                "Default",
                "{controller}/{id}",
                new { id = RouteParameter.Optional }
                );
            builder.UseWebApi(config);
        }
    }
    public class Server
    {
        private ManualResetEvent resetEvent = new ManualResetEvent(false);
        private Thread thread;
        private const string ADDRESS = "http://localhost:9000/";
        public void Start()
        {
            this.thread = new Thread(() =>
                {
                    using (var host = WebApp.Start<Startup>(ADDRESS))
                    {
                        resetEvent.WaitOne(Timeout.Infinite, true);
                    }
                });
            thread.Start();
        }
        public void Stop()
        {
            resetEvent.Set();
        }
    }
}
When there is exception in controller, then Owin returns XML response like this:
<Error>
    <Message>An error has occurred.</Message>
    <ExceptionMessage>Attempted to divide by zero.</ExceptionMessage>
    <ExceptionType>System.DivideByZeroException</ExceptionType>
    <StackTrace> 
        ...
    </StackTrace>
</Error>
But i want different output - so how can i override this?