I'm guessing it's not officially supported yet as it's a bit unpredictable... In Firefox using $("#somediv").css("-moz-border-radius", "20px"); will set the border radius fine, but trying to read it back via $("#somediv").css("-moz-border-radius"); returns an empty string... However, it appears that Firefox explodes the border radius into its component parts meaning $("#somediv").css("-moz-border-radius-topleft"); will work (obviously only returns one corner's settings though).
Edit:
As Tgr points out $('#foo').css('MozBorderRadius') will let you read it back generically in Firefox. And as Bradley Mountford points out in a comment below, it looks like you can read from Webkit using the component parts too (although only chrome seems to like border-top-left-radius, where as both Chrome & Safari handle -webkit-border-top-left-radius...
So summarising, you get the following (based on your 5px setting):
In Firefox:
$("#somediv").css("MozBorderRadius"); //"5px 5px 5px 5px"
$("pre").css("-moz-border-radius-topleft"); //"5px"
In Webkit (tested in Chrome & Safari):
$("pre").css("-webkit-border-top-left-radius"); //"5px 5px"