Yes, there is a special function that can add to a Char, from the same Enum class that enumFromTo is from, named succ. Beware that it is partial: succ maxBound is undefined, so take care to check the value of the character before you apply succ. succ is indeed the same as \c -> chr (ord c + 1), as you can verify with the universe package:
> let avoidMaxBound f x = if x == maxBound then Nothing else Just (f x)
> avoidMaxBound succ == avoidMaxBound (\c -> chr (ord c + 1))
True
In fact the implementation of succ in GHC is quite close to the function you suggested:
instance Enum Char where
succ (C# c#)
| isTrue# (ord# c# /=# 0x10FFFF#) = C# (chr# (ord# c# +# 1#))
| otherwise = error ("Prelude.Enum.Char.succ: bad argument")
However, succ is not used in the implementation of enumFromTo in GHC:
instance Enum Char where
{-# INLINE enumFromTo #-}
enumFromTo (C# x) (C# y) = eftChar (ord# x) (ord# y)
{-# RULES
"eftChar" [~1] forall x y. eftChar x y = build (\c n -> eftCharFB c n x y)
#-}
-- We can do better than for Ints because we don't
-- have hassles about arithmetic overflow at maxBound
{-# INLINE [0] eftCharFB #-}
eftCharFB :: (Char -> a -> a) -> a -> Int# -> Int# -> a
eftCharFB c n x0 y = go x0
where
go x | isTrue# (x ># y) = n
| otherwise = C# (chr# x) `c` go (x +# 1#)
{-# NOINLINE [1] eftChar #-}
eftChar :: Int# -> Int# -> String
eftChar x y | isTrue# (x ># y ) = []
| otherwise = C# (chr# x) : eftChar (x +# 1#) y
If you can squint past the nastiness that exists primarily for efficiency reasons, you can see that eftChar is essentially using succ, but an inlined version of it rather than an actual call to succ (here, to avoid boxing and re-boxing the Char being manipulated).