There has been a big update on the Mailchimp API (v3.0) and many of the jQuery plugins are out of date in order to POST subscribers on form.submit().
After reading v3.0 docs:
Managing subscribers suggests the following JSON object format:
{
   "email_address": "urist.mcvankab@freddiesjokes.com", 
   "status": "subscribed", 
   "merge_fields": {
      "FNAME": "Urist", 
      "LNAME": "McVankab"
   }
}
And the following root endpoint for the API lists resource:
https://<dc>.api.mailchimp.com/3.0/
So here's my form.submit() code with the jQuery Ajax POST request:
$(document).ready(function(){
    var mcForm = $('#mailchimpForm');
    var mailchimp = {};
    mailchimp.dc='us5';
    mailchimp.id='xxxxxxxx';
    var url = '//' + mailchimp.dc + '.api.mailchimp.com/3.0/lists/' + mailchimp.id + '/members/';
    function beginMailchimpPost(data){
        var params = JSON.stringify(data);
        $.ajax({
            url: url,
            method: 'POST',
            data: params,
            dataType: 'jsonp',
            contentType: 'application/json; charset=utf-8',
            error: function(res, text){
                console.log('Err', res);
            },
            success: function(res){
                console.log('Success', res);
            }
        });
    }
});
This is the JSON.stringify(data) object:
{"email_address":"email@mail.com","status":"subscribed","merge_fields":{"FNAME":"Name","LNAME":"Last name"}}
And I'm getting the following error:
GET http://... 401 (Unauthorized)
Err Object {readyState: 4, status: 404, statusText: "error"}
What could be wrong?
Here's the link to Mailchimp's API v3.0 docs (list members collection).