Safely returned default value via generics and LINQ.  
public T ReadAppSetting<T>(string searchKey, T defaultValue, StringComparison compare = StringComparison.Ordinal)
{
    if (ConfigurationManager.AppSettings.AllKeys.Any(key => string.Compare(key, searchKey, compare) == 0)) {
        try
        { // see if it can be converted.
            var converter = TypeDescriptor.GetConverter(typeof(T));
            if (converter != null) defaultValue = (T)converter.ConvertFromString(ConfigurationManager.AppSettings.GetValues(searchKey).First());
        }
        catch { } // nothing to do just return the defaultValue
    }
    return defaultValue;
}
Used as follows:
string LogFileName = ReadAppSetting("LogFile","LogFile");
double DefaultWidth = ReadAppSetting("Width",1280.0);
double DefaultHeight = ReadAppSetting("Height",1024.0);
Color DefaultColor = ReadAppSetting("Color",Colors.Black);