LiveDemo
CREATE TABLE #tab(
   ID   INTEGER  NOT NULL PRIMARY KEY 
  ,Name VARCHAR(7) NOT NULL
);
INSERT INTO #tab(ID,Name) VALUES (1,'John');
INSERT INTO #tab(ID,Name) VALUES (2,'Jane');
INSERT INTO #tab(ID,Name) VALUES (3,'Joe');
INSERT INTO #tab(ID,Name) VALUES (4,'Jimmy');
SELECT 
    [Col] = 'Id'
   ,[Example] = STUFF((SELECT CONCAT(',', ID)
               FROM #tab
               FOR XML PATH('')), 1, 1, '')
INTO #Metadata
UNION ALL
SELECT
    [Col] = 'Name'
   ,[Example] = STUFF((SELECT CONCAT(',', Name)
               FROM #tab
               FOR XML PATH('')), 1, 1, '');
SELECT *
FROM #Metadata;
EDIT:
LiveDemo2
No more hardcoded values. Fully dynamic SQL:
CREATE TABLE #tab(
   ID   INTEGER  NOT NULL PRIMARY KEY 
  ,Name VARCHAR(7) NOT NULL
  ,Age INT NOT NULL
);
INSERT INTO #tab(ID,Name, Age) VALUES (1,'John', 14);
INSERT INTO #tab(ID,Name, Age) VALUES (2,'Jane', 23);
INSERT INTO #tab(ID,Name, Age) VALUES (3,'Joe', 34);
INSERT INTO #tab(ID,Name, Age) VALUES (4,'Jimmy', 54);
DECLARE 
  @col_name   NVARCHAR(128) = NULL,
  @table_name NVARCHAR(128) = '#tab',
  @counter    INT           = 1;
SELECT COLUMN_NAME, ORDINAL_POSITION
INTO #columns
FROM tempdb.INFORMATION_SCHEMA.COLUMNS
WHERE TABLE_NAME LIKE @table_name + '%';
SELECT @col_name = COLUMN_NAME
FROM #columns
WHERE ORDINAL_POSITION = @counter;
DECLARE @sql NVARCHAR(MAX) = 
N'SELECT 
    [Col] = ''<col_name>''
   ,[Example] = STUFF((SELECT TOP 10 CONCAT('','', <col_name>)
               FROM <table_name>
               FOR XML PATH('''')), 1, 1, '''')';
SET @sql = REPLACE(@sql, '<col_name>', @col_name);
SET @sql = REPLACE(@sql, '<table_name>', @table_name);
SET @counter += 1;
WHILE @counter <= (SELECT COUNT(*) FROM #columns)
BEGIN
  SELECT @col_name = COLUMN_NAME
  FROM #columns
  WHERE ORDINAL_POSITION = @counter;
  SET @sql += 
  N'UNION ALL
    SELECT
    [Col] = ''<col_name>''
   ,[Example] = STUFF((SELECT TOP 10 CONCAT('','', <col_name>)
               FROM <table_name>
               FOR XML PATH('''')), 1, 1, '''')';
  SET @sql = REPLACE(@sql, '<col_name>', @col_name);
  SET @sql = REPLACE(@sql, '<table_name>', @table_name);
  SET @counter += 1;
END
CREATE TABLE #Metadata(Col NVARCHAR(128), Example NVARCHAR(MAX));
INSERT INTO #Metadata(col, Example)
EXEC [dbo].[sp_executesql]
      @sql;
SELECT *
FROM #Metadata;