There are a variety of options.
First include <boost/algorithm/string/find.hpp> and <string>.
Then use ifind_first as follows.
std::string str = ...;
std::string subStr = ...;
boost::iterator_range<std::string::const_iterator> rng;
rng = boost::ifind_first(str, subStr);
struct ci_char_traits : public char_traits<char>
{
    static bool eq(char c1, char c2) { return toupper(c1) == toupper(c2); }
    static bool ne(char c1, char c2) { return toupper(c1) != toupper(c2); }
    static bool lt(char c1, char c2) { return toupper(c1) <  toupper(c2); }
    static int compare(const char* s1, const char* s2, size_t n)
    {
        while( n-- != 0 )
        {
            if( toupper(*s1) < toupper(*s2) ) return -1;
            if( toupper(*s1) > toupper(*s2) ) return 1;
            ++s1; ++s2;
        }
        return 0;
    }
    static const char* find(const char* s, int n, char a)
    {
        while(n-- > 0 && toupper(*s) != toupper(a))
        {
            ++s;
        }
        return s;
    }
};
typedef std::basic_string<char, ci_char_traits> ci_string;
Then you can use it as follows.
ci_string str = ...;
std::string subStr = ...;
auto pos = str.find(subStr.c_str());
Note that the problem with this is the fact that you need to use the c_str function when calling the find function or when assigning a ci_string to a std::string or when assigning a std::string to a ci_string.
Use std::search with a custom predicate
As suggested in the article Case insensitive std::string.find().