If you can either assume that vector<bool> is using contiguous byte-sized elements for storage, or if you can consider using something like vector<uint8_t> instead, then this example should give you a good starting point:
static size_t count_equal(const vector<uint8_t> &vec1, const vector<uint8_t> &vec2)
{
    assert(vec1.size() == vec2.size());         // vectors must be same size
    const size_t n = vec1.size();
    const size_t max_block_size = 255 * 16;     // max block size before possible overflow
    __m128i vcount = _mm_setzero_si128();
    size_t i, count = 0;
    for (i = 0; i + 16 <= n; )                  // for each block
    {
        size_t m = std::min(n, i + max_block_size);
        for ( ; i + 16 <= m; i += 16)           // for each vector in block
        {
            __m128i v1 = _mm_loadu_si128((__m128i *)&vec1[i]);
            __m128i v2 = _mm_loadu_si128((__m128i *)&vec2[i]);
            __m128i vcmp = _mm_cmpeq_epi8(v1, v2);
            vcount = _mm_sub_epi8(vcount, vcmp);
        }
        vcount = _mm_sad_epu8(vcount, _mm_setzero_si128());
        count += _mm_extract_epi16(vcount, 0) + _mm_extract_epi16(vcount, 4);
        vcount = _mm_setzero_si128();           // update count from current block
    }
    vcount = _mm_sad_epu8(vcount, _mm_setzero_si128());
    count += _mm_extract_epi16(vcount, 0) + _mm_extract_epi16(vcount, 4);
    for ( ; i < n; ++i)                         // deal with any remaining partial vector
    {
        count += (vec1[i] == vec2[i]);
    }
    return count;
}
Note that this is using vector<uint8_t>. If you really have to use vector<bool> and can guarantee that the elements will always be contiguous and byte-sized then you'll just need to coerce the vector<bool> into a const uint8_t * or similar somehow.
Test harness:
#include <cassert>
#include <cstdlib>
#include <ctime>
#include <iostream>
#include <vector>
#include <emmintrin.h>    // SSE2
using std::vector;
static size_t count_equal_ref(const vector<uint8_t> &vec1, const vector<uint8_t> &vec2)
{
    assert(vec1.size() == vec2.size());
    const size_t n = vec1.size();
    size_t i, count = 0;
    for (i = 0 ; i < n; ++i)
    {
        count += (vec1[i] == vec2[i]);
    }
    return count;
}
static size_t count_equal(const vector<uint8_t> &vec1, const vector<uint8_t> &vec2)
{
    assert(vec1.size() == vec2.size());         // vectors must be same size
    const size_t n = vec1.size();
    const size_t max_block_size = 255 * 16;     // max block size before possible overflow
    __m128i vcount = _mm_setzero_si128();
    size_t i, count = 0;
    for (i = 0; i + 16 <= n; )                  // for each block
    {
        size_t m = std::min(n, i + max_block_size);
        for ( ; i + 16 <= m; i += 16)           // for each vector in block
        {
            __m128i v1 = _mm_loadu_si128((__m128i *)&vec1[i]);
            __m128i v2 = _mm_loadu_si128((__m128i *)&vec2[i]);
            __m128i vcmp = _mm_cmpeq_epi8(v1, v2);
            vcount = _mm_sub_epi8(vcount, vcmp);
        }
        vcount = _mm_sad_epu8(vcount, _mm_setzero_si128());
        count += _mm_extract_epi16(vcount, 0) + _mm_extract_epi16(vcount, 4);
        vcount = _mm_setzero_si128();           // update count from current block
    }
    vcount = _mm_sad_epu8(vcount, _mm_setzero_si128());
    count += _mm_extract_epi16(vcount, 0) + _mm_extract_epi16(vcount, 4);
    for ( ; i < n; ++i)                         // deal with any remaining partial vector
    {
        count += (vec1[i] == vec2[i]);
    }
    return count;
}
int main(int argc, char * argv[])
{
    size_t n = 100;
    if (argc > 1)
    {
        n = atoi(argv[1]);
    }
    vector<uint8_t> vec1(n);
    vector<uint8_t> vec2(n);
    srand((unsigned int)time(NULL));
    for (size_t i = 0; i < n; ++i)
    {
        vec1[i] = rand() & 1;
        vec2[i] = rand() & 1;
    }
    size_t n_ref = count_equal_ref(vec1, vec2);
    size_t n_test = count_equal(vec1, vec2);
    if (n_ref == n_test)
    {
        std::cout << "PASS" << std::endl;
    }
    else
    {
        std::cout << "FAIL: n_ref = " << n_ref << ", n_test = " << n_test << std::endl;
    }
    return 0;
}
Compile and run:
$ g++ -Wall -msse3 -O3 test.cpp && ./a.out
PASS