An example here from a sample test WAMP server database:-
mysql> select * from user_privileges;
| GRANTEE            | TABLE_CATALOG | PRIVILEGE_TYPE          | IS_GRANTABLE |
   +--------------------+---------------+-------------------------+--------------+
| 'root'@'localhost' | def           | SELECT                  | YES          |
| 'root'@'localhost' | def           | INSERT                  | YES          |
| 'root'@'localhost' | def           | UPDATE                  | YES          |
| 'root'@'localhost' | def           | DELETE                  | YES          |
| 'root'@'localhost' | def           | CREATE                  | YES          |
| 'root'@'localhost' | def           | DROP                    | YES          |
| 'root'@'localhost' | def           | RELOAD                  | YES          |
| 'root'@'localhost' | def           | SHUTDOWN                | YES          |
| 'root'@'localhost' | def           | PROCESS                 | YES          |
| 'root'@'localhost' | def           | FILE                    | YES          |
| 'root'@'localhost' | def           | REFERENCES              | YES          |
| 'root'@'localhost' | def           | INDEX                   | YES          |
| 'root'@'localhost' | def           | ALTER                   | YES          |
| 'root'@'localhost' | def           | SHOW DATABASES          | YES          |
| 'root'@'localhost' | def           | SUPER                   | YES          |
| 'root'@'localhost' | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'localhost' | def           | LOCK TABLES             | YES          |
| 'root'@'localhost' | def           | EXECUTE                 | YES          |
| 'root'@'localhost' | def           | REPLICATION SLAVE       | YES          |
| 'root'@'localhost' | def           | REPLICATION CLIENT      | YES          |
| 'root'@'localhost' | def           | CREATE VIEW             | YES          |
| 'root'@'localhost' | def           | SHOW VIEW               | YES          |
| 'root'@'localhost' | def           | CREATE ROUTINE          | YES          |
| 'root'@'localhost' | def           | ALTER ROUTINE           | YES          |
| 'root'@'localhost' | def           | CREATE USER             | YES          |
| 'root'@'localhost' | def           | EVENT                   | YES          |
| 'root'@'localhost' | def           | TRIGGER                 | YES          |
| 'root'@'localhost' | def           | CREATE TABLESPACE       | YES          |
| 'root'@'127.0.0.1' | def           | SELECT                  | YES          |
| 'root'@'127.0.0.1' | def           | INSERT                  | YES          |
| 'root'@'127.0.0.1' | def           | UPDATE                  | YES          |
| 'root'@'127.0.0.1' | def           | DELETE                  | YES          |
| 'root'@'127.0.0.1' | def           | CREATE                  | YES          |
| 'root'@'127.0.0.1' | def           | DROP                    | YES          |
| 'root'@'127.0.0.1' | def           | RELOAD                  | YES          |
| 'root'@'127.0.0.1' | def           | SHUTDOWN                | YES          |
| 'root'@'127.0.0.1' | def           | PROCESS                 | YES          |
| 'root'@'127.0.0.1' | def           | FILE                    | YES          |
| 'root'@'127.0.0.1' | def           | REFERENCES              | YES          |
| 'root'@'127.0.0.1' | def           | INDEX                   | YES          |
| 'root'@'127.0.0.1' | def           | ALTER                   | YES          |
| 'root'@'127.0.0.1' | def           | SHOW DATABASES          | YES          |
| 'root'@'127.0.0.1' | def           | SUPER                   | YES          |
| 'root'@'127.0.0.1' | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'127.0.0.1' | def           | LOCK TABLES             | YES          |
| 'root'@'127.0.0.1' | def           | EXECUTE                 | YES          |
| 'root'@'127.0.0.1' | def           | REPLICATION SLAVE       | YES          |
| 'root'@'127.0.0.1' | def           | REPLICATION CLIENT      | YES          |
| 'root'@'127.0.0.1' | def           | CREATE VIEW             | YES          |
| 'root'@'127.0.0.1' | def           | SHOW VIEW               | YES          |
| 'root'@'127.0.0.1' | def           | CREATE ROUTINE          | YES          |
| 'root'@'127.0.0.1' | def           | ALTER ROUTINE           | YES          |
| 'root'@'127.0.0.1' | def           | CREATE USER             | YES          |
| 'root'@'127.0.0.1' | def           | EVENT                   | YES          |
| 'root'@'127.0.0.1' | def           | TRIGGER                 | YES          |
| 'root'@'127.0.0.1' | def           | CREATE TABLESPACE       | YES          |
| 'root'@'::1'       | def           | SELECT                  | YES          |
| 'root'@'::1'       | def           | INSERT                  | YES          |
| 'root'@'::1'       | def           | UPDATE                  | YES          |
| 'root'@'::1'       | def           | DELETE                  | YES          |
| 'root'@'::1'       | def           | CREATE                  | YES          |
| 'root'@'::1'       | def           | DROP                    | YES          |
| 'root'@'::1'       | def           | RELOAD                  | YES          |
| 'root'@'::1'       | def           | SHUTDOWN                | YES          |
| 'root'@'::1'       | def           | PROCESS                 | YES          |
| 'root'@'::1'       | def           | FILE                    | YES          |
| 'root'@'::1'       | def           | REFERENCES              | YES          |
| 'root'@'::1'       | def           | INDEX                   | YES          |
| 'root'@'::1'       | def           | ALTER                   | YES          |
| 'root'@'::1'       | def           | SHOW DATABASES          | YES          |
| 'root'@'::1'       | def           | SUPER                   | YES          |
| 'root'@'::1'       | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'::1'       | def           | LOCK TABLES             | YES          |
| 'root'@'::1'       | def           | EXECUTE                 | YES          |
| 'root'@'::1'       | def           | REPLICATION SLAVE       | YES          |
| 'root'@'::1'       | def           | REPLICATION CLIENT      | YES          |
| 'root'@'::1'       | def           | CREATE VIEW             | YES          |
| 'root'@'::1'       | def           | SHOW VIEW               | YES          |
| 'root'@'::1'       | def           | CREATE ROUTINE          | YES          |
| 'root'@'::1'       | def           | ALTER ROUTINE           | YES          |
| 'root'@'::1'       | def           | CREATE USER             | YES          |
| 'root'@'::1'       | def           | EVENT                   | YES          |
| 'root'@'::1'       | def           | TRIGGER                 | YES          |
| 'root'@'::1'       | def           | CREATE TABLESPACE       | YES          |
| ''@'localhost'     | def           | USAGE                   | NO           |
+--------------------+---------------+-------------------------+--------------+
85 rows in set (0.00 sec)
And when it is given additional order by PRIVILEGE_TYPE or can be given order by 3 . Notice the 3rd column (PRIVILEGE_TYPE) getting sorted alphabetically.
mysql> select * from user_privileges order by PRIVILEGE_TYPE;
+--------------------+---------------+-------------------------+--------------+
| GRANTEE            | TABLE_CATALOG | PRIVILEGE_TYPE          | IS_GRANTABLE |
+--------------------+---------------+-------------------------+--------------+
| 'root'@'127.0.0.1' | def           | ALTER                   | YES          |
| 'root'@'::1'       | def           | ALTER                   | YES          |
| 'root'@'localhost' | def           | ALTER                   | YES          |
| 'root'@'::1'       | def           | ALTER ROUTINE           | YES          |
| 'root'@'localhost' | def           | ALTER ROUTINE           | YES          |
| 'root'@'127.0.0.1' | def           | ALTER ROUTINE           | YES          |
| 'root'@'127.0.0.1' | def           | CREATE                  | YES          |
| 'root'@'::1'       | def           | CREATE                  | YES          |
| 'root'@'localhost' | def           | CREATE                  | YES          |
| 'root'@'::1'       | def           | CREATE ROUTINE          | YES          |
| 'root'@'localhost' | def           | CREATE ROUTINE          | YES          |
| 'root'@'127.0.0.1' | def           | CREATE ROUTINE          | YES          |
| 'root'@'::1'       | def           | CREATE TABLESPACE       | YES          |
| 'root'@'localhost' | def           | CREATE TABLESPACE       | YES          |
| 'root'@'127.0.0.1' | def           | CREATE TABLESPACE       | YES          |
| 'root'@'::1'       | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'localhost' | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'127.0.0.1' | def           | CREATE TEMPORARY TABLES | YES          |
| 'root'@'localhost' | def           | CREATE USER             | YES          |
| 'root'@'127.0.0.1' | def           | CREATE USER             | YES          |
| 'root'@'::1'       | def           | CREATE USER             | YES          |
| 'root'@'localhost' | def           | CREATE VIEW             | YES          |
| 'root'@'127.0.0.1' | def           | CREATE VIEW             | YES          |
| 'root'@'::1'       | def           | CREATE VIEW             | YES          |
| 'root'@'127.0.0.1' | def           | DELETE                  | YES          |
| 'root'@'::1'       | def           | DELETE                  | YES          |
| 'root'@'localhost' | def           | DELETE                  | YES          |
| 'root'@'::1'       | def           | DROP                    | YES          |
| 'root'@'localhost' | def           | DROP                    | YES          |
| 'root'@'127.0.0.1' | def           | DROP                    | YES          |
| 'root'@'127.0.0.1' | def           | EVENT                   | YES          |
| 'root'@'::1'       | def           | EVENT                   | YES          |
| 'root'@'localhost' | def           | EVENT                   | YES          |
| 'root'@'127.0.0.1' | def           | EXECUTE                 | YES          |
| 'root'@'::1'       | def           | EXECUTE                 | YES          |
| 'root'@'localhost' | def           | EXECUTE                 | YES          |
| 'root'@'127.0.0.1' | def           | FILE                    | YES          |
| 'root'@'::1'       | def           | FILE                    | YES          |
| 'root'@'localhost' | def           | FILE                    | YES          |
| 'root'@'localhost' | def           | INDEX                   | YES          |
| 'root'@'127.0.0.1' | def           | INDEX                   | YES          |
| 'root'@'::1'       | def           | INDEX                   | YES          |
| 'root'@'::1'       | def           | INSERT                  | YES          |
| 'root'@'localhost' | def           | INSERT                  | YES          |
| 'root'@'127.0.0.1' | def           | INSERT                  | YES          |
| 'root'@'127.0.0.1' | def           | LOCK TABLES             | YES          |
| 'root'@'::1'       | def           | LOCK TABLES             | YES          |
| 'root'@'localhost' | def           | LOCK TABLES             | YES          |
| 'root'@'127.0.0.1' | def           | PROCESS                 | YES          |
| 'root'@'::1'       | def           | PROCESS                 | YES          |
| 'root'@'localhost' | def           | PROCESS                 | YES          |
| 'root'@'::1'       | def           | REFERENCES              | YES          |
| 'root'@'localhost' | def           | REFERENCES              | YES          |
| 'root'@'127.0.0.1' | def           | REFERENCES              | YES          |
| 'root'@'::1'       | def           | RELOAD                  | YES          |
| 'root'@'localhost' | def           | RELOAD                  | YES          |
| 'root'@'127.0.0.1' | def           | RELOAD                  | YES          |
| 'root'@'::1'       | def           | REPLICATION CLIENT      | YES          |
| 'root'@'localhost' | def           | REPLICATION CLIENT      | YES          |
| 'root'@'127.0.0.1' | def           | REPLICATION CLIENT      | YES          |
| 'root'@'::1'       | def           | REPLICATION SLAVE       | YES          |
| 'root'@'localhost' | def           | REPLICATION SLAVE       | YES          |
| 'root'@'127.0.0.1' | def           | REPLICATION SLAVE       | YES          |
| 'root'@'127.0.0.1' | def           | SELECT                  | YES          |
| 'root'@'::1'       | def           | SELECT                  | YES          |
| 'root'@'localhost' | def           | SELECT                  | YES          |
| 'root'@'127.0.0.1' | def           | SHOW DATABASES          |  YES          |
| 'root'@'::1'       | def           | SHOW DATABASES          | YES          |
| 'root'@'localhost' | def           | SHOW DATABASES          | YES          |
| 'root'@'127.0.0.1' | def           | SHOW VIEW               | YES          |
| 'root'@'::1'       | def           | SHOW VIEW               | YES          |
| 'root'@'localhost' | def           | SHOW VIEW               | YES          |
| 'root'@'localhost' | def           | SHUTDOWN                | YES          |
| 'root'@'127.0.0.1' | def           | SHUTDOWN                | YES          |
| 'root'@'::1'       | def           | SHUTDOWN                | YES          |
| 'root'@'::1'       | def           | SUPER                   | YES          |
| 'root'@'localhost' | def           | SUPER                   | YES          |
| 'root'@'127.0.0.1' | def           | SUPER                   | YES          |
| 'root'@'127.0.0.1' | def           | TRIGGER                 | YES          |
| 'root'@'::1'       | def           | TRIGGER                 | YES          |
| 'root'@'localhost' | def           | TRIGGER                 | YES          |
| 'root'@'::1'       | def           | UPDATE                  | YES          |
| 'root'@'localhost' | def           | UPDATE                  | YES          |
| 'root'@'127.0.0.1' | def           | UPDATE                  | YES          |
| ''@'localhost'     | def           | USAGE                   | NO           |     +--------------------+---------------+-------------------------+--------------+
85 rows in set (0.00 sec)
DEFINITIVELY, a long answer and alot of scrolling.
Also I struggled hard to pass the output of the queries to a text file.
Here is how to do that without using the annoying into outfile thing-
tee E:/sqllogfile.txt;
And when you are done, stop the logging-
tee off;
Hope it adds more clarity.