In code to load a resource in the executing assembly where my image Freq.png was in the folder Icons and defined as Resource:
this.Icon = new BitmapImage(new Uri(@"pack://application:,,,/" 
    + Assembly.GetExecutingAssembly().GetName().Name 
    + ";component/" 
    + "Icons/Freq.png", UriKind.Absolute)); 
I also made a function:
/// <summary>
/// Load a resource WPF-BitmapImage (png, bmp, ...) from embedded resource defined as 'Resource' not as 'Embedded resource'.
/// </summary>
/// <param name="pathInApplication">Path without starting slash</param>
/// <param name="assembly">Usually 'Assembly.GetExecutingAssembly()'. If not mentionned, I will use the calling assembly</param>
/// <returns></returns>
public static BitmapImage LoadBitmapFromResource(string pathInApplication, Assembly assembly = null)
{
    if (assembly == null)
    {
        assembly = Assembly.GetCallingAssembly();
    }
    if (pathInApplication[0] == '/')
    {
        pathInApplication = pathInApplication.Substring(1);
    }
    return new BitmapImage(new Uri(@"pack://application:,,,/" + assembly.GetName().Name + ";component/" + pathInApplication, UriKind.Absolute)); 
}
Usage (assumption you put the function in a ResourceHelper class):
this.Icon = ResourceHelper.LoadBitmapFromResource("Icons/Freq.png");
Note: see MSDN Pack URIs in WPF:
 pack://application:,,,/ReferencedAssembly;component/Subfolder/ResourceFile.xaml