Well, what you're asking isn't fool proof.  What you're referring to is Libraries.  And the problem with Libraries is that there can be more than one folder included in a Library.
However, there is a reasonable way to get what you want.  Windows provides ShellSpecialFolder constants you can enumerate using the Shell.Application COM object.  The constant for the Documents Library is 0x05.  Here's a PowerShell command example:
powershell "(new-object -COM Shell.Application).Namespace(0x05).Self.Path"
My home computer has a 120GB SSD boot drive and a 2TB D: drive.  So I have my Documents library pointing to D:\Documents.  The command above prints D:\Documents as you'd hope it would.
If you're prefer Windows Script Host over PowerShell (as WSH is much faster), you can write a hybrid batch + JScript script to accomplish the same task.
@if (@CodeSection == @Batch) @then
@echo off & setlocal
rem // cscript re-evaluates this script with the JScript interpreter
cscript /nologo /e:JScript "%~f0"
goto :EOF
@end // end Batch / begin JScript hybrid chimera
WSH.Echo(WSH.CreateObject('Shell.Application').Namespace(0x05).Self.Path);
You might also consider letting the user browse to his desired save location, defaulting to 0x05 for Documents.