Significance
To the question:
...does an empty else clause have any significance?
in the context of if { ... } else {} the answer is no. Compilers will probably optimize your else out. Unless you put actual statements (assert, print, error handling) the executable will be virtually identical.
Benefits
To the question:
What are the benefits of an empty else clause in an else if construct?
the answer is discussed at length on this Stack Overflow post. See MISRA publication MISRA C:2012, 15.7 (All if…else if constructs shall be terminated with an else statement).
It applies to if { ... } else if { ... } else {} construct, not if { ... } else {} construct.
Style
An else { /* no statement */ } in immensely better than an else statement. It does prevent dangling else closures (else not followed by {}) which are downright dangerous since they may mislead a reader of what else actually applies to, and is prone to maintenance errors.
You will find more programming styles1 than you have engineers in a room. May I suggest:
int main() {
    int i = 11;
    if (i > 100) {
        i = 100;
    } else if (i < 0) {
        i = 0;
    }
    cout << i << endl;
}
1 each individual, plus one for the consensus.