You might use a specific way to run two or more commands or programms, such as the  threading library of Python. Here you have a wide example about how it works.
import threading
import time
exitFlag = 0
class myThread (threading.Thread):
    def __init__(self, threadID, name, counter):
        threading.Thread.__init__(self)
        self.threadID = threadID
        self.name = name
        self.counter = counter
    def run(self):
        print "Starting " + self.name
        print_time(self.name, self.counter, 5)
        print "Exiting " + self.name
def print_time(threadName, delay, counter):
    while counter:
        if exitFlag:
            threadName.exit()
        time.sleep(delay)
        print "%s: %s" % (threadName, time.ctime(time.time()))
        counter -= 1
# Create new threads
thread1 = myThread(1, "Thread-1", 1)
thread2 = myThread(2, "Thread-2", 2)
# Start new Threads
thread1.start()
thread2.start()
print "Exiting Main Thread"
Then, your code could be something like this:
import threading
class myThread (threading.Thread):
    def __init__(self, command):
        threading.Thread.__init__(self)
        self.cmd = command
    def run(self):
        print "Starting " + self.cmd
        os.system(self.cmd)
        print "Exiting " + self.cmd
lstCmd=["a.exe","b.exe","ping 192.168.0.10","some command"]
# Create new threads
thread1 = myThread(lstCmd[0])
thread2 = myThread(lstCmd[1])
thread3 = myThread(lstCmd[2])
thread4 = myThread(lstCmd[3])
# Start new Threads
thread1.start()
thread2.start()
thread3.start()
thread4.start()