Just posting this here and might help the others:
I got this error when we had an outage a while ago, and tried to restart the slon replication service as the replication is NOT really replicating the data from MASTER to SLAVE:
FATAL  localListenThread: "select "_MY_DATABASE_copy".cleanupNodelock(); insert into "_MY_DATABASE_copy".sl_nodelock values (    1, 0, "pg_catalog".pg_backend_pid()); " - ERROR:  duplicate key value violates unique constraint "sl_nodelock-pkey"
DEBUG2 slon_abort() from pid=xxxx
DEBUG1 slon: shutdown requested