You can achieve this by creating a triangle using borders if you create an element with a very wide bottom border:
HTML 
<div id="container">
  <div id="mask">
  </div>
</div>
CSS 
#container {
  position: relative;
  width: 100%;
  height: 25em;
  overflow: hidden;
  ...
}
#mask {
  /* position the element on top */
  position: absolute;
  width: 0;
  height: 0;
  bottom: 0;
  left: 0;
  z-index: 1;
  /* create a triangle using borders */
  border-style: solid;
  border-color: YOUR_BACKGROUND_COLOUR transparent;
  /* A fallback for browsers that don't support vw */
  border-width: 0 2560px 5em 0;
  /* make the border take the full width of the screen: http://caniuse.com/#feat=viewport-units */
  border-width: 0 100vw 10em 0;
}
DEMO
http://codepen.io/Godwin/pen/PzPMBQ?editors=1100
However, like @kthornbloom said, unless you absolutely need to show a skew, it would be best practice to just let IE8 show a rectangle instead. You'll have more success making the page dependably responsive if you use transforms.